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The most important commercial sources are nickel-copper deposits found in the Sudbury Basin, Ontario, and the Norilsk–Talnakh deposits in Siberia.

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Cobaltite-Gersdorffite Series. See also the chemically very similar Glaucodot and Alloclasite. Compare 'UM1966-01-As:CoNiS' and 'UM1982-09-S:AsCoFeNi'.

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Several triclinic and monoclinic polytypes are known. The structure of wollastonite contains dreier single chains with the repeating unit (Si3O9)6-.